[(E)-10-(2,6-Dimethylphenylimino)-9-methyl-9,10-dihydrophenanthren-9-olato]pentamethyldialuminum(III)
نویسندگان
چکیده
منابع مشابه
Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
In the title compound, C(22)H(16)N(2)OS(2), the phenanthrene ring is nearly perpendicular to the phenyl ring, making a dihedral angle of 87.2 (2)°. Intra-molecular N-H⋯O inter-actions are present. In the crystal structure, the mol-ecules are linked through inter-molecular C-H⋯O inter-actions. The crystal structure is also stabilized by C-H⋯π inter-actions and weak π-π contacts [centroid-centroi...
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In the title mol-ecule, C18H13BrO2, the anthracene unit forms an angle of 46.91 (2)° with the mean plane of the methyl acrylate moiety. In the crystal, the mol-ecules arrange themselves into strands parallel to [010] and, due to the crystal symmetry, there are eight strands crossing the unit cell. In each strand, mol-ecules form short C-H⋯O and C-H⋯π contacts and have their anthracene groups pa...
متن کامل[(E)-10-(2,6-Dimethylphenylimino)-9-methyl-9,10-dihydrophenanthren-9-olato]pentamethyldialuminum(III)
The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra-hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom from the ligand as well as by two methyl-C atoms. In the ligand, the dihedral angle between the tw...
متن کامل10-Methyl-9-phenoxycarbonylacridinium trifluoromethanesulfonate monohydrate
In the crystal structure of the title compound, C(21)H(16)NO(2) (+)·CF(3)SO(3) (-)·H(2)O, the anions and the water mol-ecules are linked by O-H⋯O inter-actions, while the cations form inversion dimers through π-π inter-actions between acridine ring systems. These dimers are linked by C-H⋯O and C-F⋯π inter-actions to adjacent anions, and by C-H⋯π inter-actions to neighboring cations. The water m...
متن کامل10-Methyl-9-(2-nitrophenoxycarbonyl)acridinium trifluoromethanesulfonate
The crystal structure of the title compound, C(21)H(15)N(2)O(4) (+)·CF(3)O(3)S(-), is stabilized by C-H⋯O and C-H⋯F hydrogen bonds, by C-F⋯π, N-O⋯π and S-O⋯π inter-actions, and by O⋯O [2.70 (4) Å] and O⋯F [2.85 (1) or 2.92 (1) Å] contacts; π-π interactions are also present. In the packing of the mol-ecules, acridine units are either parallel or inclined at an angle of 12.5 (1)°. The nitrophenox...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811036312